Basic information:
Product
name: Diphenylamine
An
English alias: N-Phenylaniline, N-Phenylbenzeneamine
Chemical
Formula: C12H11N
Molecular
Weight: 169.23
CAS
NO: 122-39-4
Appearance:
Diphenylamine is white to pale red crystals. It has floral scent. It is easy to
change color when exposes the light. Diphenylamine is soluble in ether,
benzene, glacial acetic acid and carbon disulfide, 1g Diphenylamine dissolve in
2.2ml of ethanol, 4.5ml of acetone, but it is insoluble in water. With strong
acids to form salts. The relative density is 1.16. Melting point is 54 to 55 ℃. Boiling point is 302 ℃. Flash
point is 153 ℃.
Diphenylamine has low toxicity and median lethal dose (rat, oral) is 3000mg/kg.
Diphenylamine has strong Irritation.
Storage:
sealed cool stored.
Uses:
Diphenylamine is used to nitrates, perchlorates and other oxidizing substances
test. It is also used to the Determination of iridium catalyst and Nitrate
photometric. Diphenylamine is a kind of Redox indicator. Sometimes
Diphenylamine used as Haploid breeding medium and manufacture of dyes.
Diphenylamine is also a stabilizer of Nitrocellulose, explosives, collodion.
HAZARDS of Diphenylamine:
Health
Hazard: No occupational poisoning reported. The product manufacturing process
can containing 4 - amino biphenyl, the latter should be noted that
carcinogenicity.
Explosion
Hazards: Diphenylamine is flammable, irritating.
First aid measures:
Skin
contact: Remove contaminated clothing, mobile water rinse.
Eye
contact: Did eyelid, mobile or saline irrigation water. See Doctor.
Inhalation:
from the scene to fresh air. See Doctor.
Ingestion:
drink plenty of water, induce vomiting. See Doctor.
Fire-fighting measures:
Hazardous
characteristics: Case of fire, combustible high fever. Powder can form
explosive mixtures with air, when it reaches a certain concentration, the case
of Mars will be an explosion.
Hazardous
combustion products: carbon monoxide, carbon dioxide, nitrogen oxides.
Extinguishing
Media: water spray, foam, dry powder, carbon dioxide, sand
Fire
fighting methods: firefighters are required to wear gas masks at a safe
distance, standing the wind on fire.
Leakage accidental: isolation leakage polluted area, restricting access. Cut off the
fire source. Recommended emergency personnel wearing a dust mask (full cover),
wear protective clothing. With clean shovel collection in a dry, clean, covered
containers, transfer to a safe place. If spills are too large, the recycling or
collection should be shipped to the waste disposal sites.
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